Abstract
The first aromatic benzicorrole termed naphthicorrole was synthesized with a carbon donor containing more than six members. Its oxidized (enedione-embedded) porphyrinoid was also obtained using different meso-aryl substitutions under sequential oxidation conditions. The resulting enedione motif of the nonaromatic porphyrinoid was regioselective to the C2 position for S or N nucleophiles. Thus, the oxidized porphyrinoid was tested as a built-in linker for biomolecules. The progress of the reaction was visually monitored due to their different conjugation pathways.
Original language | English |
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Pages (from-to) | 722-726 |
Number of pages | 5 |
Journal | Journal of Organic Chemistry |
Volume | 88 |
Issue number | 1 |
DOIs | |
State | Published - 6 Jan 2023 |
Bibliographical note
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