Synthesis and thermal properties of epoxidized vegetable oil

Soo Jin Park; Fan Long Jin; Jae Rock Lee

doi:10.1002/marc.200300191

Synthesis and thermal properties of epoxidized vegetable oil

Soo Jin Park, Fan Long Jin, Jae Rock Lee

Korea Research Institute of Chemical Technology

Research output: Contribution to journal › Article › peer-review

208 Scopus citations

Abstract

The novel potential epoxy resins, epoxidized soybean oil (ESO) and epoxidized castor oil (ECO), were synthesized and characterized. The cationic polymerization of ESO and ECO with a latent thermal catalyst. N-benzylpyrazinium hexafluoroantimonate (BPH), was initiated at 80 and 50 °C, respectively. The cured ECO samples showed a higher T_g and lower coefficient of thermal expansion than those of ESO, due to the higher intermolecular interaction in the ECO/BPH system.

Original language	English
Pages (from-to)	724-727
Number of pages	4
Journal	Macromolecular Rapid Communications
Volume	25
Issue number	6
DOIs	https://doi.org/10.1002/marc.200300191
State	Published - 19 Mar 2004
Externally published	Yes

Keywords

Catalysts
Cationic polymerization
Crosslinking
Density
Thermal properties

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10.1002/marc.200300191

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abstract = "The novel potential epoxy resins, epoxidized soybean oil (ESO) and epoxidized castor oil (ECO), were synthesized and characterized. The cationic polymerization of ESO and ECO with a latent thermal catalyst. N-benzylpyrazinium hexafluoroantimonate (BPH), was initiated at 80 and 50 °C, respectively. The cured ECO samples showed a higher Tg and lower coefficient of thermal expansion than those of ESO, due to the higher intermolecular interaction in the ECO/BPH system.",

keywords = "Catalysts, Cationic polymerization, Crosslinking, Density, Thermal properties",

author = "Park, {Soo Jin} and Jin, {Fan Long} and Lee, {Jae Rock}",

year = "2004",

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doi = "10.1002/marc.200300191",

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T1 - Synthesis and thermal properties of epoxidized vegetable oil

AU - Park, Soo Jin

AU - Jin, Fan Long

AU - Lee, Jae Rock

PY - 2004/3/19

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N2 - The novel potential epoxy resins, epoxidized soybean oil (ESO) and epoxidized castor oil (ECO), were synthesized and characterized. The cationic polymerization of ESO and ECO with a latent thermal catalyst. N-benzylpyrazinium hexafluoroantimonate (BPH), was initiated at 80 and 50 °C, respectively. The cured ECO samples showed a higher Tg and lower coefficient of thermal expansion than those of ESO, due to the higher intermolecular interaction in the ECO/BPH system.

AB - The novel potential epoxy resins, epoxidized soybean oil (ESO) and epoxidized castor oil (ECO), were synthesized and characterized. The cationic polymerization of ESO and ECO with a latent thermal catalyst. N-benzylpyrazinium hexafluoroantimonate (BPH), was initiated at 80 and 50 °C, respectively. The cured ECO samples showed a higher Tg and lower coefficient of thermal expansion than those of ESO, due to the higher intermolecular interaction in the ECO/BPH system.

KW - Catalysts

KW - Cationic polymerization

KW - Crosslinking

KW - Density

KW - Thermal properties

UR - http://www.scopus.com/inward/record.url?scp=4544386859&partnerID=8YFLogxK

U2 - 10.1002/marc.200300191

DO - 10.1002/marc.200300191

M3 - Article

AN - SCOPUS:4544386859

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SP - 724

EP - 727

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 6

ER -

Synthesis and thermal properties of epoxidized vegetable oil

Abstract

Keywords

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