Synthesis and characterization of a novel silicon-containing epoxy resin

Soo Jin Park, Fan Long Jin, Jae Rock Lee

Research output: Contribution to journalArticlepeer-review

32 Scopus citations

Abstract

A novel silicon-containing epoxy resin, the diglycidylether of bisphenol A-silicon (DGEBA-Si), was synthesized and characterized. The properties of the DGEBA-Si epoxy resin cured with 4,4-diaminodiphenyl methane (DDM), including its cure behavior, glass transition temperature, thermal stability, and mechanical strength were investigated. The char yield of the DGEBA-Si/DDM system was higher than that of a commercial DGEBA/DDM system, indicating that the DGEBA-Si epoxy resin showed good flame-retardance. The cured DGEBA-Si/DDM specimens possessed lower glass transition temperatures and higher mechanical properties than DGEBA/DDM specimens. These features were attributed to the introduction of siloxane groups into the main chain of the epoxy resin, which resulted in the improved flexibility of the cured DGEBA-Si/DDM system.

Original languageEnglish
Pages (from-to)8-13
Number of pages6
JournalMacromolecular Research
Volume13
Issue number1
DOIs
StatePublished - Feb 2005
Externally publishedYes

Keywords

  • Epoxy
  • Mechanical properties
  • Silicon
  • Synthesis
  • Thermal properties

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