Abstract
C4 alkenes are generally used to produce synthetic rubbers, plastics, and other important chemicals. Transition metal oxides are traditionally used as catalysts to produce C4 alkenes from n-butane by oxidative dehydrogenation (ODH). On the other hand, metal-free carbon nanomaterials are receiving much attention as catalysts for ODH due to their environmental benignity, corrosion resistance, and unique surface properties. In this work, a systematic methodology was designed to measure conversion of the reactants, selectivity to main products, and other catalytic performances of a set of carbon catalysts, including graphite and activated carbon. The experiments were carried out under a wide range of reaction conditions, and the reaction mechanism and kinetics were developed based on Marsvan Krevelen interpretation of the experimental results.
Original language | English |
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Pages (from-to) | 3417-3424 |
Number of pages | 8 |
Journal | Korean Journal of Chemical Engineering |
Volume | 33 |
Issue number | 12 |
DOIs | |
State | Published - 1 Dec 2016 |
Bibliographical note
Publisher Copyright:© 2016, Korean Institute of Chemical Engineers, Seoul, Korea.
Keywords
- Carbon Material
- Catalyst
- Kinetic
- Modeling
- Oxidative Dehydrogenation