Preparation of porous ultra-fine poly(vinyl cinnamate) fibers

Won Seok Lyoo; Ji Ho Youk; Sung Won Lee; Won Ho Park

doi:10.1016/j.matlet.2005.06.027

Preparation of porous ultra-fine poly(vinyl cinnamate) fibers

Won Seok Lyoo, Ji Ho Youk, Sung Won Lee, Won Ho Park

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

In this study, a new method of preparing porous ultra-fine fibers via photo-crosslinking was developed. Ultra-fine poly(vinyl cinnamate)/poly(3- hydroxybutyrate-co-3-hydroxyvalerate) (PVCi/PHBV) blend fibers were electrospun and then the PVCi was photo-crosslinked by UV irradiation. PVCi and PHBV were immiscible and the phase separation proceeded during the electrospinning process. After the photo-crosslinking of PVCi, PHBV was extracted from the blend fibers with chloroform. The average pore sizes in the remaining ultra-fine PVCi fibers were increased with increasing the content of PHBV in the ultra-fine PVCi/PHBV fibers.

Original language	English
Pages (from-to)	3558-3562
Number of pages	5
Journal	Materials Letters
Volume	59
Issue number	28
DOIs	https://doi.org/10.1016/j.matlet.2005.06.027
State	Published - Dec 2005

Bibliographical note

Funding Information:
This work was supported by grant no. RTI-01-04 from the Regional Technology Innovation Program of the Ministry of Commerce, Industry and Energy (MOCIE).

Keywords

Electrospinning
Photo-crosslinking
Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)
Poly(vinyl cinnamate)
Porous ultra-fine fibers

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10.1016/j.matlet.2005.06.027

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@article{2b0de4fab17a4b73876aa659e0586abb,

title = "Preparation of porous ultra-fine poly(vinyl cinnamate) fibers",

abstract = "In this study, a new method of preparing porous ultra-fine fibers via photo-crosslinking was developed. Ultra-fine poly(vinyl cinnamate)/poly(3- hydroxybutyrate-co-3-hydroxyvalerate) (PVCi/PHBV) blend fibers were electrospun and then the PVCi was photo-crosslinked by UV irradiation. PVCi and PHBV were immiscible and the phase separation proceeded during the electrospinning process. After the photo-crosslinking of PVCi, PHBV was extracted from the blend fibers with chloroform. The average pore sizes in the remaining ultra-fine PVCi fibers were increased with increasing the content of PHBV in the ultra-fine PVCi/PHBV fibers.",

keywords = "Electrospinning, Photo-crosslinking, Poly(3-hydroxybutyrate-co-3-hydroxyvalerate), Poly(vinyl cinnamate), Porous ultra-fine fibers",

author = "Lyoo, {Won Seok} and Youk, {Ji Ho} and Lee, {Sung Won} and Park, {Won Ho}",

note = "Funding Information: This work was supported by grant no. RTI-01-04 from the Regional Technology Innovation Program of the Ministry of Commerce, Industry and Energy (MOCIE).",

year = "2005",

month = dec,

doi = "10.1016/j.matlet.2005.06.027",

language = "English",

volume = "59",

pages = "3558--3562",

journal = "Materials Letters",

issn = "0167-577X",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Preparation of porous ultra-fine poly(vinyl cinnamate) fibers

AU - Lyoo, Won Seok

AU - Youk, Ji Ho

AU - Lee, Sung Won

AU - Park, Won Ho

N1 - Funding Information: This work was supported by grant no. RTI-01-04 from the Regional Technology Innovation Program of the Ministry of Commerce, Industry and Energy (MOCIE).

PY - 2005/12

Y1 - 2005/12

N2 - In this study, a new method of preparing porous ultra-fine fibers via photo-crosslinking was developed. Ultra-fine poly(vinyl cinnamate)/poly(3- hydroxybutyrate-co-3-hydroxyvalerate) (PVCi/PHBV) blend fibers were electrospun and then the PVCi was photo-crosslinked by UV irradiation. PVCi and PHBV were immiscible and the phase separation proceeded during the electrospinning process. After the photo-crosslinking of PVCi, PHBV was extracted from the blend fibers with chloroform. The average pore sizes in the remaining ultra-fine PVCi fibers were increased with increasing the content of PHBV in the ultra-fine PVCi/PHBV fibers.

AB - In this study, a new method of preparing porous ultra-fine fibers via photo-crosslinking was developed. Ultra-fine poly(vinyl cinnamate)/poly(3- hydroxybutyrate-co-3-hydroxyvalerate) (PVCi/PHBV) blend fibers were electrospun and then the PVCi was photo-crosslinked by UV irradiation. PVCi and PHBV were immiscible and the phase separation proceeded during the electrospinning process. After the photo-crosslinking of PVCi, PHBV was extracted from the blend fibers with chloroform. The average pore sizes in the remaining ultra-fine PVCi fibers were increased with increasing the content of PHBV in the ultra-fine PVCi/PHBV fibers.

KW - Electrospinning

KW - Photo-crosslinking

KW - Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)

KW - Poly(vinyl cinnamate)

KW - Porous ultra-fine fibers

UR - http://www.scopus.com/inward/record.url?scp=27144525205&partnerID=8YFLogxK

U2 - 10.1016/j.matlet.2005.06.027

DO - 10.1016/j.matlet.2005.06.027

M3 - Article

AN - SCOPUS:27144525205

SN - 0167-577X

VL - 59

SP - 3558

EP - 3562

JO - Materials Letters

JF - Materials Letters

IS - 28

ER -

Preparation of porous ultra-fine poly(vinyl cinnamate) fibers

Abstract

Bibliographical note

Keywords

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