Preparation and analyses of MnO2/carbon composites for rechargeable lithium-air battery

Ku Bong Chung, Ju Kyung Shin, Tae Young Jang, Dong Kyun Noh, Yongsug Tak, Sung Hyeon Baeck

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

MnO2-carbon composites with various Mn/C ratios were prepared by precipitation method. The composites were cast onto Ni foam to be evaluated as cathodes of Li-air battery. Charge-discharge tests were carried out by using a Swagelok type cell in an 1 M LiPF6 in a mixture of propylene carbonate (PC), ethylene carbonate (EC) and diethyl carbonate (DEC) (1:1:2 weight ratio). The influence of Mn/C ratio on both capacity and charge/discharge behavior was investigated. The cycle performance of Li/O2 batteries was strongly dependent on Mn/C ratio. With increasing amount of MnO2, the cycle performance of Li/O2 batteries improved. The influence of electrolyte amount was also investigated, and the best cycle performance was achieved when 90 μL of electrolyte was used.

Original languageEnglish
Pages (from-to)54-58
Number of pages5
JournalReviews on Advanced Materials Science
Volume28
Issue number1
StatePublished - Jun 2011

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