Polymer-Supported Ionic Liquids: Imidazolium Salts as Catalysts for Nucleophilic Substitution Reactions Including Fluorinations

Dong Wook Kim; Dae Yoon Chi

doi:10.1002/anie.200352760

Polymer-Supported Ionic Liquids: Imidazolium Salts as Catalysts for Nucleophilic Substitution Reactions Including Fluorinations

Dong Wook Kim, Dae Yoon Chi

Inha University

Research output: Contribution to journal › Article › peer-review

250 Scopus citations

Abstract

Ionic liquids obtain firm support: Polymer-supported imidazolium salts are shown to be highly efficient catalysts for fluorination and other nucleophilic substitution reactions. The polystyrene-based ionic materials catalyze fluorination reactions (such as that shown in the scheme; X = BF₄, OTf) in very high yield, and can be reused for many such reactions.

Original language	English
Pages (from-to)	483-485
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	4
DOIs	https://doi.org/10.1002/anie.200352760
State	Published - 16 Jan 2004

Keywords

Fluorination
Heterogeneous catalysis
Ionic liquids nucleophilic substitution
Polymers

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abstract = "Ionic liquids obtain firm support: Polymer-supported imidazolium salts are shown to be highly efficient catalysts for fluorination and other nucleophilic substitution reactions. The polystyrene-based ionic materials catalyze fluorination reactions (such as that shown in the scheme; X = BF4, OTf) in very high yield, and can be reused for many such reactions.",

keywords = "Fluorination, Heterogeneous catalysis, Ionic liquids nucleophilic substitution, Polymers",

author = "Kim, {Dong Wook} and Chi, {Dae Yoon}",

year = "2004",

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AU - Chi, Dae Yoon

PY - 2004/1/16

Y1 - 2004/1/16

N2 - Ionic liquids obtain firm support: Polymer-supported imidazolium salts are shown to be highly efficient catalysts for fluorination and other nucleophilic substitution reactions. The polystyrene-based ionic materials catalyze fluorination reactions (such as that shown in the scheme; X = BF4, OTf) in very high yield, and can be reused for many such reactions.

AB - Ionic liquids obtain firm support: Polymer-supported imidazolium salts are shown to be highly efficient catalysts for fluorination and other nucleophilic substitution reactions. The polystyrene-based ionic materials catalyze fluorination reactions (such as that shown in the scheme; X = BF4, OTf) in very high yield, and can be reused for many such reactions.

KW - Fluorination

KW - Heterogeneous catalysis

KW - Ionic liquids nucleophilic substitution

KW - Polymers

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M3 - Article

AN - SCOPUS:0842285877

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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ER -

Polymer-Supported Ionic Liquids: Imidazolium Salts as Catalysts for Nucleophilic Substitution Reactions Including Fluorinations

Abstract

Keywords

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