Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

Hosung Ki; Tae Wu Kim; Jiwon Moon; Jungmin Kim; Yunbeom Lee; Jun Heo; Kyung Hwan Kim; Qingyu Kong; Dmitry Khakhulin; Gemma Newby; Joonghan Kim; Jeongho Kim; Michael Wulff; Hyotcherl Ihee

doi:10.1039/d2cc02438a

Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

Hosung Ki, Tae Wu Kim, Jiwon Moon, Jungmin Kim, Yunbeom Lee, Jun Heo, Kyung Hwan Kim, Qingyu Kong, Dmitry Khakhulin, Gemma Newby, Joonghan Kim, Jeongho Kim, Michael Wulff, Hyotcherl Ihee

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5 Scopus citations

Abstract

The photoactivation mechanism of Os₃(CO)₁₂ at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os₃(CO)₁₁ with a ligand vacancy at the axial position.

Original language	English
Pages (from-to)	7380-7383
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	53
DOIs	https://doi.org/10.1039/d2cc02438a
State	Published - 8 Jun 2022

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© 2022 The Royal Society of Chemistry.

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title = "Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography",

abstract = "The photoactivation mechanism of Os3(CO)12 at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os3(CO)11 with a ligand vacancy at the axial position.",

author = "Hosung Ki and Kim, {Tae Wu} and Jiwon Moon and Jungmin Kim and Yunbeom Lee and Jun Heo and Kim, {Kyung Hwan} and Qingyu Kong and Dmitry Khakhulin and Gemma Newby and Joonghan Kim and Jeongho Kim and Michael Wulff and Hyotcherl Ihee",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

month = jun,

day = "8",

doi = "10.1039/d2cc02438a",

language = "English",

volume = "58",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

AU - Ki, Hosung

AU - Kim, Tae Wu

AU - Moon, Jiwon

AU - Kim, Jungmin

AU - Lee, Yunbeom

AU - Heo, Jun

AU - Kim, Kyung Hwan

AU - Kong, Qingyu

AU - Khakhulin, Dmitry

AU - Newby, Gemma

AU - Kim, Joonghan

AU - Kim, Jeongho

AU - Wulff, Michael

AU - Ihee, Hyotcherl

PY - 2022/6/8

Y1 - 2022/6/8

N2 - The photoactivation mechanism of Os3(CO)12 at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os3(CO)11 with a ligand vacancy at the axial position.

AB - The photoactivation mechanism of Os3(CO)12 at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os3(CO)11 with a ligand vacancy at the axial position.

UR - http://www.scopus.com/inward/record.url?scp=85132223689&partnerID=8YFLogxK

U2 - 10.1039/d2cc02438a

DO - 10.1039/d2cc02438a

M3 - Article

C2 - 35695475

AN - SCOPUS:85132223689

SN - 1359-7345

VL - 58

SP - 7380

EP - 7383

JO - Chemical Communications

JF - Chemical Communications

IS - 53

ER -

Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

Abstract

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