Mango Seed-Derived Hybrid Composites and Sodium Alginate Beads for the Efficient Uptake of 2,4,6-Trichlorophenol from Simulated Wastewater

In this study, mango seed shell (MS)-based hybrid composite and composite beads (FeCl₃-NaBH₄/MS and Na-Alginate/MS) were designed. Batch and column experimental analyses were performed for the uptake of 2,4,6-trichlorophenol (2,4,6-TCP) from wastewater. The physicochemical characteristics of both composites were also examined. From the batch adsorption experiments, the best adsorption capacities of 28.77 mg/g and 27.42 mg/g were observed in basic media (pH 9–10) at 308 K for FeCl₃-NaBH₄/MS and 333 K for Na-Alginate/MS with 25 mg/L of 2,4,6-TCP concentration for 120 min. The rate of reaction was satisfactorily followed by the pseudo-second-order kinetics. Equilibrium models revealed that the mechanism of reaction followed the Langmuir isotherm. The thermodynamic study also indicated that the nature of the reaction was exothermic and spontaneous with both adsorbents. Desorption experiments were also carried out to investigate the reliability and reusability of the composites. Furthermore, the efficiency of the adsorbents was checked in the presence of different electrolytes and heavy metals. From the batch experimental study, the FeCl₃-NaBH₄/MS composite proved to be the best adsorbent for the removal of the 2,4,6-TCP pollutant, hence it is further selected for fixed-bed column experimentation. The column study data were analyzed using the BDST and Thomas models and the as-selected FeCl₃-NaBH₄/MS hybrid composites showed satisfactory results for the fixed-bed adsorption of the 2,4,6-TPC contaminants.