Ion conductivity of polymer electrolytes based on PEO containing Li salt and additive salt

Seok Kim; Eun Ju Hwang; Hyung Il Kim; Soo Jin Park

doi:10.4028/www.scientific.net/SSP.119.119

Ion conductivity of polymer electrolytes based on PEO containing Li salt and additive salt

Seok Kim, Eun Ju Hwang, Hyung Il Kim, Soo Jin Park

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Solid type polymer electrolyte is in progress of research and development in many ways to improve an ionic conductivity to attain 10^-3 S/cm which is possibility of practical use of secondary lithium ion battery. There are two major methods of improving ionic conductivity; either lowering Tg of polymer or lowering the energy of ionic movement. In this work, the solid type polymer electrolyte (SPE) composites, which were composed of poly(ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, lithium salt, and 1-ethyl-3-methylimidazolium hexafluorophosphate (EMI-PF₆) as a filler in order to improve the ion conductivity of the SPE, were prepared. The influence of EMI-PF6 contents on the ionic conductivity of the SPE composites was investigated in this work. As a result, the ionic conductivity of the SPE was enhanced by an increase in EMI-PF6 content, and showed the highest ionic conductivity at 40 wt.%. It was thought that there was a close correlation between the mobility of Li⁺ and EMI content in a SPE composite system.

Original language	English
Title of host publication	Nanocomposites and Nanoporous Materials
Editors	Chang Kyu Rhee
Publisher	Trans Tech Publications Ltd
Pages	119-122
Number of pages	4
ISBN (Print)	9783908451273
DOIs	https://doi.org/10.4028/www.scientific.net/SSP.119.119
State	Published - 2007
Event	7th International Symposium on Nanocomposites and Nanoporous Materials, ISNAM 2006 - Gyeongju, Korea, Republic of Duration: 15 Feb 2006 → 17 Feb 2006

Publication series

Name	Solid State Phenomena
Volume	119
ISSN (Print)	1012-0394
ISSN (Electronic)	1662-9779

Conference

Conference	7th International Symposium on Nanocomposites and Nanoporous Materials, ISNAM 2006
Country/Territory	Korea, Republic of
City	Gyeongju
Period	15/02/06 → 17/02/06

Bibliographical note

Publisher Copyright:
© (2007) Trans Tech Publications, Switzerland.

Keywords

1-ethyl-3-methylimidazolium hexafluorophosphate
Lithium salt
Polyethylene oxide

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.4028/www.scientific.net/SSP.119.119

Cite this

@inproceedings{616944a4ecde4749a32442e8045dcf92,

title = "Ion conductivity of polymer electrolytes based on PEO containing Li salt and additive salt",

abstract = "Solid type polymer electrolyte is in progress of research and development in many ways to improve an ionic conductivity to attain 10-3 S/cm which is possibility of practical use of secondary lithium ion battery. There are two major methods of improving ionic conductivity; either lowering Tg of polymer or lowering the energy of ionic movement. In this work, the solid type polymer electrolyte (SPE) composites, which were composed of poly(ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, lithium salt, and 1-ethyl-3-methylimidazolium hexafluorophosphate (EMI-PF6) as a filler in order to improve the ion conductivity of the SPE, were prepared. The influence of EMI-PF6 contents on the ionic conductivity of the SPE composites was investigated in this work. As a result, the ionic conductivity of the SPE was enhanced by an increase in EMI-PF6 content, and showed the highest ionic conductivity at 40 wt.%. It was thought that there was a close correlation between the mobility of Li+ and EMI content in a SPE composite system.",

keywords = "1-ethyl-3-methylimidazolium hexafluorophosphate, Lithium salt, Polyethylene oxide",

author = "Seok Kim and Hwang, {Eun Ju} and Kim, {Hyung Il} and Park, {Soo Jin}",

note = "Publisher Copyright: {\textcopyright} (2007) Trans Tech Publications, Switzerland.; 7th International Symposium on Nanocomposites and Nanoporous Materials, ISNAM 2006 ; Conference date: 15-02-2006 Through 17-02-2006",

year = "2007",

doi = "10.4028/www.scientific.net/SSP.119.119",

language = "English",

isbn = "9783908451273",

series = "Solid State Phenomena",

publisher = "Trans Tech Publications Ltd",

pages = "119--122",

editor = "Rhee, {Chang Kyu}",

booktitle = "Nanocomposites and Nanoporous Materials",

}

Kim, S, Hwang, EJ, Kim, HI & Park, SJ 2007, Ion conductivity of polymer electrolytes based on PEO containing Li salt and additive salt. in CK Rhee (ed.), Nanocomposites and Nanoporous Materials. Solid State Phenomena, vol. 119, Trans Tech Publications Ltd, pp. 119-122, 7th International Symposium on Nanocomposites and Nanoporous Materials, ISNAM 2006, Gyeongju, Korea, Republic of, 15/02/06. https://doi.org/10.4028/www.scientific.net/SSP.119.119

Ion conductivity of polymer electrolytes based on PEO containing Li salt and additive salt. / Kim, Seok; Hwang, Eun Ju; Kim, Hyung Il et al.
Nanocomposites and Nanoporous Materials. ed. / Chang Kyu Rhee. Trans Tech Publications Ltd, 2007. p. 119-122 (Solid State Phenomena; Vol. 119).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Ion conductivity of polymer electrolytes based on PEO containing Li salt and additive salt

AU - Kim, Seok

AU - Hwang, Eun Ju

AU - Kim, Hyung Il

AU - Park, Soo Jin

N1 - Publisher Copyright: © (2007) Trans Tech Publications, Switzerland.

PY - 2007

Y1 - 2007

N2 - Solid type polymer electrolyte is in progress of research and development in many ways to improve an ionic conductivity to attain 10-3 S/cm which is possibility of practical use of secondary lithium ion battery. There are two major methods of improving ionic conductivity; either lowering Tg of polymer or lowering the energy of ionic movement. In this work, the solid type polymer electrolyte (SPE) composites, which were composed of poly(ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, lithium salt, and 1-ethyl-3-methylimidazolium hexafluorophosphate (EMI-PF6) as a filler in order to improve the ion conductivity of the SPE, were prepared. The influence of EMI-PF6 contents on the ionic conductivity of the SPE composites was investigated in this work. As a result, the ionic conductivity of the SPE was enhanced by an increase in EMI-PF6 content, and showed the highest ionic conductivity at 40 wt.%. It was thought that there was a close correlation between the mobility of Li+ and EMI content in a SPE composite system.

AB - Solid type polymer electrolyte is in progress of research and development in many ways to improve an ionic conductivity to attain 10-3 S/cm which is possibility of practical use of secondary lithium ion battery. There are two major methods of improving ionic conductivity; either lowering Tg of polymer or lowering the energy of ionic movement. In this work, the solid type polymer electrolyte (SPE) composites, which were composed of poly(ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, lithium salt, and 1-ethyl-3-methylimidazolium hexafluorophosphate (EMI-PF6) as a filler in order to improve the ion conductivity of the SPE, were prepared. The influence of EMI-PF6 contents on the ionic conductivity of the SPE composites was investigated in this work. As a result, the ionic conductivity of the SPE was enhanced by an increase in EMI-PF6 content, and showed the highest ionic conductivity at 40 wt.%. It was thought that there was a close correlation between the mobility of Li+ and EMI content in a SPE composite system.

KW - 1-ethyl-3-methylimidazolium hexafluorophosphate

KW - Lithium salt

KW - Polyethylene oxide

UR - http://www.scopus.com/inward/record.url?scp=84954518891&partnerID=8YFLogxK

U2 - 10.4028/www.scientific.net/SSP.119.119

DO - 10.4028/www.scientific.net/SSP.119.119

M3 - Conference contribution

AN - SCOPUS:84954518891

SN - 9783908451273

T3 - Solid State Phenomena

SP - 119

EP - 122

BT - Nanocomposites and Nanoporous Materials

A2 - Rhee, Chang Kyu

PB - Trans Tech Publications Ltd

T2 - 7th International Symposium on Nanocomposites and Nanoporous Materials, ISNAM 2006

Y2 - 15 February 2006 through 17 February 2006

ER -

Ion conductivity of polymer electrolytes based on PEO containing Li salt and additive salt

Abstract

Publication series

Conference

Bibliographical note

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this