TY - JOUR
T1 - Influence of thermal treatment of nano-scaled silica on interfacial adhesion properties of the silica/rubber compounding
AU - Park, Soo Jin
AU - Jin, Sung Yeol
AU - Kaang, Shinyoung
PY - 2005/5/25
Y1 - 2005/5/25
N2 - In this work, the effect of thermal treatment on crosslink density and adhesion properties of nano-scaled silica/rubber compounding are investigated. The chemical structures and surface properties of modified silicas are studied in terms of Fourier transform-IR (FT-IR), solid-state 29Si-NMR spectroscopy, and surface free energy, respectively. Also, the mechanical interfacial properties of the silica/ rubber compounding are determined by the crosslink density and tearing energy (GIIIC). As a result, it was found that the thermally treated silicas became hydrophobic in nature, due to the condensation of surface hydroxyls and the formation of siloxane bond. From which, the increase of the siloxane bond on the silica surfaces led to an improvement of the dispersion of silicas in a rubber matrix, finally resulting in improving the tearing energy in a compounding system.
AB - In this work, the effect of thermal treatment on crosslink density and adhesion properties of nano-scaled silica/rubber compounding are investigated. The chemical structures and surface properties of modified silicas are studied in terms of Fourier transform-IR (FT-IR), solid-state 29Si-NMR spectroscopy, and surface free energy, respectively. Also, the mechanical interfacial properties of the silica/ rubber compounding are determined by the crosslink density and tearing energy (GIIIC). As a result, it was found that the thermally treated silicas became hydrophobic in nature, due to the condensation of surface hydroxyls and the formation of siloxane bond. From which, the increase of the siloxane bond on the silica surfaces led to an improvement of the dispersion of silicas in a rubber matrix, finally resulting in improving the tearing energy in a compounding system.
KW - Mechanical interfacial properties
KW - SBR
KW - Silicas
KW - Surface properties
KW - Thermal treatment
UR - http://www.scopus.com/inward/record.url?scp=18844421357&partnerID=8YFLogxK
U2 - 10.1016/j.msea.2005.03.012
DO - 10.1016/j.msea.2005.03.012
M3 - Article
AN - SCOPUS:18844421357
SN - 0921-5093
VL - 398
SP - 137
EP - 141
JO - Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing
JF - Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing
IS - 1-2
ER -