Fine-tuning the 3D structure of nonfullerene electron acceptors toward high-performance polymer solar cells

Haiyan Li, Ye Jin Hwang, Brett A.E. Courtright, Frank N. Eberle, Selvam Subramaniyan, Samson A. Jenekhe

Research output: Contribution to journalArticlepeer-review

162 Scopus citations

Abstract

Arylene linkers in a series of new tetraazabenzodifluoranthene diimide dimers enable tuning of the 3D molecular structure of nonfullerene electron acceptors, facilitating observation of dramatic variation of the power conversion efficiency from 2.6% to 6.4% as the twist angle between the monomeric building blocks in the dimer is varied.

Original languageEnglish
Pages (from-to)3266-3272
Number of pages7
JournalAdvanced Materials
Volume27
Issue number21
DOIs
StatePublished - 1 Jun 2015
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords

  • 3D structures
  • n-type organic semiconductors
  • nonfullerene electron acceptors
  • polymer solar cells
  • tetraazabenzodifluoranthene diimide

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