Fabrication of 3D honeycomb-like porous polyurethane-functionalized reduced graphene oxide for detection of dopamine

A. T.Ezhil Vilian; Suyeong An; Sang Rak Choe; Cheol Hwan Kwak; Yun Suk Huh; Jonghwi Lee; Young Kyu Han

doi:10.1016/j.bios.2016.06.022

Fabrication of 3D honeycomb-like porous polyurethane-functionalized reduced graphene oxide for detection of dopamine

A. T.Ezhil Vilian, Suyeong An, Sang Rak Choe, Cheol Hwan Kwak, Yun Suk Huh, Jonghwi Lee, Young Kyu Han

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

A three dimensional reduced graphene oxide/polyurethane (RGO-PU) porous material with connected pores was prepared by physical adsorption of RGO onto the surface of porous PU. The porous PU was prepared by directional melt crystallization of a solvent, which produced high pores with controlled orientation. The prepared RGO-PU was characterized by scanning electron microscopy, spectroscopy and electro-chemical methods. The RGO-PU porous material revealed better electrochemical performance, which might be attributed to the robust structure, superior conductivity, large surface area, and good flexibility. Differential pulse voltammetry (DPV) analysis of DA using the RGO-PU exhibited a linear response range over a wide DA concentration of 100–1150 pM, with the detection limit of 1 pM. This sensor exhibited outstanding anti-interference ability towards co-existing molecules with good stability, sensitivity, and reproducibility. Furthermore, the fabricated sensor was successfully applied for the quantitative analysis of DA in human serum and urine samples with acceptable recovery, which indicates its feasibility for practical application.

Original language	English
Pages (from-to)	122-128
Number of pages	7
Journal	Biosensors and Bioelectronics
Volume	86
DOIs	https://doi.org/10.1016/j.bios.2016.06.022
State	Published - 15 Dec 2016

Bibliographical note

Publisher Copyright:
© 2016 Elsevier B.V.

Keywords

Dopamine
Electrocatalysis
Electrochemical sensor
Polyurethane
Reduced graphene oxide

Access to Document

10.1016/j.bios.2016.06.022

Cite this

@article{071c3208a93a4bfb9fc37208dfdc692f,

title = "Fabrication of 3D honeycomb-like porous polyurethane-functionalized reduced graphene oxide for detection of dopamine",

abstract = "A three dimensional reduced graphene oxide/polyurethane (RGO-PU) porous material with connected pores was prepared by physical adsorption of RGO onto the surface of porous PU. The porous PU was prepared by directional melt crystallization of a solvent, which produced high pores with controlled orientation. The prepared RGO-PU was characterized by scanning electron microscopy, spectroscopy and electro-chemical methods. The RGO-PU porous material revealed better electrochemical performance, which might be attributed to the robust structure, superior conductivity, large surface area, and good flexibility. Differential pulse voltammetry (DPV) analysis of DA using the RGO-PU exhibited a linear response range over a wide DA concentration of 100–1150 pM, with the detection limit of 1 pM. This sensor exhibited outstanding anti-interference ability towards co-existing molecules with good stability, sensitivity, and reproducibility. Furthermore, the fabricated sensor was successfully applied for the quantitative analysis of DA in human serum and urine samples with acceptable recovery, which indicates its feasibility for practical application.",

keywords = "Dopamine, Electrocatalysis, Electrochemical sensor, Polyurethane, Reduced graphene oxide",

author = "Vilian, {A. T.Ezhil} and Suyeong An and Choe, {Sang Rak} and Kwak, {Cheol Hwan} and Huh, {Yun Suk} and Jonghwi Lee and Han, {Young Kyu}",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2016",

month = dec,

day = "15",

doi = "10.1016/j.bios.2016.06.022",

language = "English",

volume = "86",

pages = "122--128",

journal = "Biosensors and Bioelectronics",

issn = "0956-5663",

publisher = "Elsevier Ltd.",

}

TY - JOUR

T1 - Fabrication of 3D honeycomb-like porous polyurethane-functionalized reduced graphene oxide for detection of dopamine

AU - Vilian, A. T.Ezhil

AU - An, Suyeong

AU - Choe, Sang Rak

AU - Kwak, Cheol Hwan

AU - Huh, Yun Suk

AU - Lee, Jonghwi

AU - Han, Young Kyu

PY - 2016/12/15

Y1 - 2016/12/15

N2 - A three dimensional reduced graphene oxide/polyurethane (RGO-PU) porous material with connected pores was prepared by physical adsorption of RGO onto the surface of porous PU. The porous PU was prepared by directional melt crystallization of a solvent, which produced high pores with controlled orientation. The prepared RGO-PU was characterized by scanning electron microscopy, spectroscopy and electro-chemical methods. The RGO-PU porous material revealed better electrochemical performance, which might be attributed to the robust structure, superior conductivity, large surface area, and good flexibility. Differential pulse voltammetry (DPV) analysis of DA using the RGO-PU exhibited a linear response range over a wide DA concentration of 100–1150 pM, with the detection limit of 1 pM. This sensor exhibited outstanding anti-interference ability towards co-existing molecules with good stability, sensitivity, and reproducibility. Furthermore, the fabricated sensor was successfully applied for the quantitative analysis of DA in human serum and urine samples with acceptable recovery, which indicates its feasibility for practical application.

AB - A three dimensional reduced graphene oxide/polyurethane (RGO-PU) porous material with connected pores was prepared by physical adsorption of RGO onto the surface of porous PU. The porous PU was prepared by directional melt crystallization of a solvent, which produced high pores with controlled orientation. The prepared RGO-PU was characterized by scanning electron microscopy, spectroscopy and electro-chemical methods. The RGO-PU porous material revealed better electrochemical performance, which might be attributed to the robust structure, superior conductivity, large surface area, and good flexibility. Differential pulse voltammetry (DPV) analysis of DA using the RGO-PU exhibited a linear response range over a wide DA concentration of 100–1150 pM, with the detection limit of 1 pM. This sensor exhibited outstanding anti-interference ability towards co-existing molecules with good stability, sensitivity, and reproducibility. Furthermore, the fabricated sensor was successfully applied for the quantitative analysis of DA in human serum and urine samples with acceptable recovery, which indicates its feasibility for practical application.

KW - Dopamine

KW - Electrocatalysis

KW - Electrochemical sensor

KW - Polyurethane

KW - Reduced graphene oxide

UR - http://www.scopus.com/inward/record.url?scp=84975893879&partnerID=8YFLogxK

U2 - 10.1016/j.bios.2016.06.022

DO - 10.1016/j.bios.2016.06.022

M3 - Article

C2 - 27344607

AN - SCOPUS:84975893879

SN - 0956-5663

VL - 86

SP - 122

EP - 128

JO - Biosensors and Bioelectronics

JF - Biosensors and Bioelectronics

ER -

Fabrication of 3D honeycomb-like porous polyurethane-functionalized reduced graphene oxide for detection of dopamine

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this