Evaluation of Menthol-Based Hydrophobic Deep Eutectic Solvents for the Extraction of Bisphenol A from Environment Water

Yena An; Kyung Ho Row

doi:10.1080/00032719.2020.1811716

Evaluation of Menthol-Based Hydrophobic Deep Eutectic Solvents for the Extraction of Bisphenol A from Environment Water

Yena An, Kyung Ho Row

Inha University

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Deep eutectic solvents (DES) which possess hydrophobicity were synthesized from various carboxylic acid or fatty acids and menthol to remove bisphenol A, a micropollutant present in water-based environments, via liquid–liquid extraction. The bisphenol A concentration was measured quantitatively by ultraviolet-visible spectroscopy. The structure and properties of the DES were examined by Fourier transform infrared spectroscopy and ¹H nuclear magnetic resonance spectroscopy, and the interaction of the cephalic compound was investigated. The menthol–propionic acid and menthol–formic acid DES provided the satisfactory extraction performance and several parameters, including the type and volume, stirring speed, and time of the extraction procedure, were optimized. Excellent recovery rates of 98.2%–99.0% for bisphenol A were obtained under the optimized conditions.

Original language	English
Pages (from-to)	1533-1545
Number of pages	13
Journal	Analytical Letters
Volume	54
Issue number	9
DOIs	https://doi.org/10.1080/00032719.2020.1811716
State	Published - 2021

Bibliographical note

Publisher Copyright:
© 2020 Taylor & Francis Group, LLC.

Keywords

Bisphenol A
eco-friendly solvent
hydrophobic deep eutectic solvent
liquid–liquid extraction

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10.1080/00032719.2020.1811716

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title = "Evaluation of Menthol-Based Hydrophobic Deep Eutectic Solvents for the Extraction of Bisphenol A from Environment Water",

abstract = "Deep eutectic solvents (DES) which possess hydrophobicity were synthesized from various carboxylic acid or fatty acids and menthol to remove bisphenol A, a micropollutant present in water-based environments, via liquid–liquid extraction. The bisphenol A concentration was measured quantitatively by ultraviolet-visible spectroscopy. The structure and properties of the DES were examined by Fourier transform infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy, and the interaction of the cephalic compound was investigated. The menthol–propionic acid and menthol–formic acid DES provided the satisfactory extraction performance and several parameters, including the type and volume, stirring speed, and time of the extraction procedure, were optimized. Excellent recovery rates of 98.2%–99.0% for bisphenol A were obtained under the optimized conditions.",

keywords = "Bisphenol A, eco-friendly solvent, hydrophobic deep eutectic solvent, liquid–liquid extraction",

author = "Yena An and Row, {Kyung Ho}",

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year = "2021",

doi = "10.1080/00032719.2020.1811716",

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volume = "54",

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T1 - Evaluation of Menthol-Based Hydrophobic Deep Eutectic Solvents for the Extraction of Bisphenol A from Environment Water

AU - An, Yena

AU - Row, Kyung Ho

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Y1 - 2021

N2 - Deep eutectic solvents (DES) which possess hydrophobicity were synthesized from various carboxylic acid or fatty acids and menthol to remove bisphenol A, a micropollutant present in water-based environments, via liquid–liquid extraction. The bisphenol A concentration was measured quantitatively by ultraviolet-visible spectroscopy. The structure and properties of the DES were examined by Fourier transform infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy, and the interaction of the cephalic compound was investigated. The menthol–propionic acid and menthol–formic acid DES provided the satisfactory extraction performance and several parameters, including the type and volume, stirring speed, and time of the extraction procedure, were optimized. Excellent recovery rates of 98.2%–99.0% for bisphenol A were obtained under the optimized conditions.

AB - Deep eutectic solvents (DES) which possess hydrophobicity were synthesized from various carboxylic acid or fatty acids and menthol to remove bisphenol A, a micropollutant present in water-based environments, via liquid–liquid extraction. The bisphenol A concentration was measured quantitatively by ultraviolet-visible spectroscopy. The structure and properties of the DES were examined by Fourier transform infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy, and the interaction of the cephalic compound was investigated. The menthol–propionic acid and menthol–formic acid DES provided the satisfactory extraction performance and several parameters, including the type and volume, stirring speed, and time of the extraction procedure, were optimized. Excellent recovery rates of 98.2%–99.0% for bisphenol A were obtained under the optimized conditions.

KW - Bisphenol A

KW - eco-friendly solvent

KW - hydrophobic deep eutectic solvent

KW - liquid–liquid extraction

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DO - 10.1080/00032719.2020.1811716

M3 - Article

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SN - 0003-2719

VL - 54

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JO - Analytical Letters

JF - Analytical Letters

IS - 9

ER -

Evaluation of Menthol-Based Hydrophobic Deep Eutectic Solvents for the Extraction of Bisphenol A from Environment Water

Abstract

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Keywords

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