Effects of silane-modified carbon nanotubes on flexural and fracture behaviors of carbon nanotube-modified epoxy/basalt composites

M. T. Kim, K. Y. Rhee, S. J. Park, D. Hui

Research output: Contribution to journalArticlepeer-review

127 Scopus citations

Abstract

We investigated the effects of carbon nanotube (CNT) modification with silane on the flexural and fracture behaviors of modified carbon nanotube epoxy/basalt (CNT/epoxy/basalt) composites. Flexural and mode I fracture tests were performed using acid-treated and silane-treated CNT/epoxy/basalt composites, respectively. FT-IR analysis was conducted to determine the chemical change on the surface of basalt fiber due to the silane modification. After the fracture tests, the fracture surfaces of the CNT/epoxy/basalt composites were examined with scanning electron microscopy (SEM) to investigate the fracture mechanisms of the CNT/epoxy/basalt composites, depending on the CNT modification. The results show that the flexural modulus and strength of silane-treated CNT/epoxy/basalt composites are ∼10% and ∼14% greater, respectively, than those of acid-treated CNT/epoxy/basalt composites. The fracture toughness G Ic of silane-treated CNT/epoxy/basalt composites was ∼40% greater than that of acid-treated CNT/epoxy/basalt composites. SEM examination revealed that the improvement in the flexural and fracture properties of silane-treated CNT/epoxy/basalt composites occurred due to enhanced dispersion and interfacial interaction between the silane-modified CNTs and the epoxy.

Original languageEnglish
Pages (from-to)2298-2302
Number of pages5
JournalComposites Part B: Engineering
Volume43
Issue number5
DOIs
StatePublished - Jul 2012

Bibliographical note

Funding Information:
This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2010-0023106).

Keywords

  • A. Polymer-matrix composites
  • B. Mechanical properties
  • E. Surface treatments

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