Effect of zeolite as a green catalyst and nucleation agent on the physical properties of poly(Ethylene 2,5-furan-dicarboxylate)

Jeyoung Park; Dongyeop X. Oh; Taeho Kim; Sung Yeon Hwang

doi:10.4028/www.scientific.net/KEM.773.88

Effect of zeolite as a green catalyst and nucleation agent on the physical properties of poly(Ethylene 2,5-furan-dicarboxylate)

Jeyoung Park
, Dongyeop X. Oh
, Taeho Kim
, Sung Yeon Hwang

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

In this study, poly(ethylene 2,5-furan dicarboxylate) (PEF) was synthesized from biomass-based dimethyl furan-2,5-dicarboxylate using different-sized zeolites, with substituted ions such as Li and K, as efficient green catalysts for in situ polymerization. The Z5Ali catalyst yielded the PEF biopolyester with the highest weight-average molecular weight among all the samples: 53,800 g/mol. From their TGA curves, it was confirmed that the PEF sample with ZA5Li as the catalyst showed an increased thermal stability compared to homo-PEF. Generally, homo-PEF exhibited a very low melt-crystallization rate with low enthalpy. However, all the PEF samples using zeolite as the catalyst formed endotherms I and II. This result was attributed to the fact that zeolite affects the melt and recrystallization of imperfect crystals due to physical hindrance.

Original language	English
Title of host publication	Applied Engineering, Materials and Mechanics II
Editors	Jong Wan Hu
Publisher	Trans Tech Publications Ltd
Pages	88-93
Number of pages	6
ISBN (Print)	9783035713374
DOIs	https://doi.org/10.4028/www.scientific.net/KEM.773.88
State	Published - 2018
Externally published	Yes
Event	3rd International Conference on Applied Engineering, Materials and Mechanics, ICAEMM 2018 - Okinawa Island, Japan Duration: 20 Apr 2018 → 22 Apr 2018

Publication series

Name	Key Engineering Materials
Volume	773 KEM
ISSN (Print)	1013-9826
ISSN (Electronic)	1662-9795

Conference

Conference	3rd International Conference on Applied Engineering, Materials and Mechanics, ICAEMM 2018
Country/Territory	Japan
City	Okinawa Island
Period	20/04/18 → 22/04/18

Bibliographical note

Publisher Copyright:
© 2018 Trans Tech Publications, Switzerland.

Keywords

Bioplastics
Green catalyst
Hetero cyclic monomer
Zeolite

Access to Document

10.4028/www.scientific.net/KEM.773.88

Cite this

Park, J., Oh, D. X., Kim, T., & Hwang, S. Y. (2018). Effect of zeolite as a green catalyst and nucleation agent on the physical properties of poly(Ethylene 2,5-furan-dicarboxylate). In J. W. Hu (Ed.), Applied Engineering, Materials and Mechanics II (pp. 88-93). (Key Engineering Materials; Vol. 773 KEM). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/KEM.773.88

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title = "Effect of zeolite as a green catalyst and nucleation agent on the physical properties of poly(Ethylene 2,5-furan-dicarboxylate)",

abstract = "In this study, poly(ethylene 2,5-furan dicarboxylate) (PEF) was synthesized from biomass-based dimethyl furan-2,5-dicarboxylate using different-sized zeolites, with substituted ions such as Li and K, as efficient green catalysts for in situ polymerization. The Z5Ali catalyst yielded the PEF biopolyester with the highest weight-average molecular weight among all the samples: 53,800 g/mol. From their TGA curves, it was confirmed that the PEF sample with ZA5Li as the catalyst showed an increased thermal stability compared to homo-PEF. Generally, homo-PEF exhibited a very low melt-crystallization rate with low enthalpy. However, all the PEF samples using zeolite as the catalyst formed endotherms I and II. This result was attributed to the fact that zeolite affects the melt and recrystallization of imperfect crystals due to physical hindrance.",

keywords = "Bioplastics, Green catalyst, Hetero cyclic monomer, Zeolite",

author = "Jeyoung Park and Oh, \{Dongyeop X.\} and Taeho Kim and Hwang, \{Sung Yeon\}",

note = "Publisher Copyright: {\textcopyright} 2018 Trans Tech Publications, Switzerland.; 3rd International Conference on Applied Engineering, Materials and Mechanics, ICAEMM 2018 ; Conference date: 20-04-2018 Through 22-04-2018",

year = "2018",

doi = "10.4028/www.scientific.net/KEM.773.88",

language = "English",

isbn = "9783035713374",

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}

Park, J, Oh, DX, Kim, T & Hwang, SY 2018, Effect of zeolite as a green catalyst and nucleation agent on the physical properties of poly(Ethylene 2,5-furan-dicarboxylate). in JW Hu (ed.), Applied Engineering, Materials and Mechanics II. Key Engineering Materials, vol. 773 KEM, Trans Tech Publications Ltd, pp. 88-93, 3rd International Conference on Applied Engineering, Materials and Mechanics, ICAEMM 2018, Okinawa Island, Japan, 20/04/18. https://doi.org/10.4028/www.scientific.net/KEM.773.88

Effect of zeolite as a green catalyst and nucleation agent on the physical properties of poly(Ethylene 2,5-furan-dicarboxylate). / Park, Jeyoung; Oh, Dongyeop X.; Kim, Taeho et al.
Applied Engineering, Materials and Mechanics II. ed. / Jong Wan Hu. Trans Tech Publications Ltd, 2018. p. 88-93 (Key Engineering Materials; Vol. 773 KEM).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Effect of zeolite as a green catalyst and nucleation agent on the physical properties of poly(Ethylene 2,5-furan-dicarboxylate)

AU - Park, Jeyoung

AU - Oh, Dongyeop X.

AU - Kim, Taeho

AU - Hwang, Sung Yeon

PY - 2018

Y1 - 2018

N2 - In this study, poly(ethylene 2,5-furan dicarboxylate) (PEF) was synthesized from biomass-based dimethyl furan-2,5-dicarboxylate using different-sized zeolites, with substituted ions such as Li and K, as efficient green catalysts for in situ polymerization. The Z5Ali catalyst yielded the PEF biopolyester with the highest weight-average molecular weight among all the samples: 53,800 g/mol. From their TGA curves, it was confirmed that the PEF sample with ZA5Li as the catalyst showed an increased thermal stability compared to homo-PEF. Generally, homo-PEF exhibited a very low melt-crystallization rate with low enthalpy. However, all the PEF samples using zeolite as the catalyst formed endotherms I and II. This result was attributed to the fact that zeolite affects the melt and recrystallization of imperfect crystals due to physical hindrance.

AB - In this study, poly(ethylene 2,5-furan dicarboxylate) (PEF) was synthesized from biomass-based dimethyl furan-2,5-dicarboxylate using different-sized zeolites, with substituted ions such as Li and K, as efficient green catalysts for in situ polymerization. The Z5Ali catalyst yielded the PEF biopolyester with the highest weight-average molecular weight among all the samples: 53,800 g/mol. From their TGA curves, it was confirmed that the PEF sample with ZA5Li as the catalyst showed an increased thermal stability compared to homo-PEF. Generally, homo-PEF exhibited a very low melt-crystallization rate with low enthalpy. However, all the PEF samples using zeolite as the catalyst formed endotherms I and II. This result was attributed to the fact that zeolite affects the melt and recrystallization of imperfect crystals due to physical hindrance.

KW - Bioplastics

KW - Green catalyst

KW - Hetero cyclic monomer

KW - Zeolite

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DO - 10.4028/www.scientific.net/KEM.773.88

M3 - Conference contribution

AN - SCOPUS:85052745166

SN - 9783035713374

T3 - Key Engineering Materials

SP - 88

EP - 93

BT - Applied Engineering, Materials and Mechanics II

A2 - Hu, Jong Wan

PB - Trans Tech Publications Ltd

T2 - 3rd International Conference on Applied Engineering, Materials and Mechanics, ICAEMM 2018

Y2 - 20 April 2018 through 22 April 2018

ER -

Effect of zeolite as a green catalyst and nucleation agent on the physical properties of poly(Ethylene 2,5-furan-dicarboxylate)

Abstract

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Bibliographical note

Keywords

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