Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes

Jin Kyun Lee; Matthew J. Fuchter; Rachel M. Williamson; Gary A. Leeke; Edward J. Bush; Ian F. McConvey; Simon Saubern; John H. Ryan; Andrew B. Holmes

doi:10.1039/b808374f

Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes

Jin Kyun Lee
, Matthew J. Fuchter
, Rachel M. Williamson
, Gary A. Leeke
, Edward J. Bush
, Ian F. McConvey
, Simon Saubern
, John H. Ryan
, Andrew B. Holmes

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A high yielding, batch mode synthesis of diaryl ethers and sulfides by an S_NAr fluoride-mediated process in scCO₂ has been developed; the use of a polymer-supported imidazolium fluoride reagent in batch mode led to the development of a fixed-bed continuous flow process, with high conversions.

Original language	English
Pages (from-to)	4780-4782
Number of pages	3
Journal	Chemical Communications
Issue number	39
DOIs	https://doi.org/10.1039/b808374f
State	Published - 2008
Externally published	Yes

Access to Document

10.1039/b808374f

Cite this

@article{016b5034664d41eaa14137b9e76678cb,

title = "Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes",

abstract = "A high yielding, batch mode synthesis of diaryl ethers and sulfides by an SNAr fluoride-mediated process in scCO2 has been developed; the use of a polymer-supported imidazolium fluoride reagent in batch mode led to the development of a fixed-bed continuous flow process, with high conversions.",

author = "Lee, \{Jin Kyun\} and Fuchter, \{Matthew J.\} and Williamson, \{Rachel M.\} and Leeke, \{Gary A.\} and Bush, \{Edward J.\} and McConvey, \{Ian F.\} and Simon Saubern and Ryan, \{John H.\} and Holmes, \{Andrew B.\}",

year = "2008",

doi = "10.1039/b808374f",

language = "English",

pages = "4780--4782",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "39",

}

TY - JOUR

T1 - Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes

AU - Lee, Jin Kyun

AU - Fuchter, Matthew J.

AU - Williamson, Rachel M.

AU - Leeke, Gary A.

AU - Bush, Edward J.

AU - McConvey, Ian F.

AU - Saubern, Simon

AU - Ryan, John H.

AU - Holmes, Andrew B.

PY - 2008

Y1 - 2008

N2 - A high yielding, batch mode synthesis of diaryl ethers and sulfides by an SNAr fluoride-mediated process in scCO2 has been developed; the use of a polymer-supported imidazolium fluoride reagent in batch mode led to the development of a fixed-bed continuous flow process, with high conversions.

AB - A high yielding, batch mode synthesis of diaryl ethers and sulfides by an SNAr fluoride-mediated process in scCO2 has been developed; the use of a polymer-supported imidazolium fluoride reagent in batch mode led to the development of a fixed-bed continuous flow process, with high conversions.

UR - https://www.scopus.com/pages/publications/54749138355

U2 - 10.1039/b808374f

DO - 10.1039/b808374f

M3 - Article

C2 - 18830491

AN - SCOPUS:54749138355

SN - 1359-7345

SP - 4780

EP - 4782

JO - Chemical Communications

JF - Chemical Communications

IS - 39

ER -

Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes

Abstract

Access to Document

Other files and links

Fingerprint

Cite this