Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes

Jin Kyun Lee; Matthew J. Fuchter; Rachel M. Williamson; Gary A. Leeke; Edward J. Bush; Ian F. McConvey; Simon Saubern; John H. Ryan; Andrew B. Holmes

doi:10.1039/b808374f

Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes

Jin Kyun Lee, Matthew J. Fuchter, Rachel M. Williamson, Gary A. Leeke, Edward J. Bush, Ian F. McConvey, Simon Saubern, John H. Ryan, Andrew B. Holmes

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

A high yielding, batch mode synthesis of diaryl ethers and sulfides by an S_NAr fluoride-mediated process in scCO₂ has been developed; the use of a polymer-supported imidazolium fluoride reagent in batch mode led to the development of a fixed-bed continuous flow process, with high conversions.

Original language	English
Pages (from-to)	4780-4782
Number of pages	3
Journal	Chemical Communications
Issue number	39
DOIs	https://doi.org/10.1039/b808374f
State	Published - 2008
Externally published	Yes

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title = "Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes",

abstract = "A high yielding, batch mode synthesis of diaryl ethers and sulfides by an SNAr fluoride-mediated process in scCO2 has been developed; the use of a polymer-supported imidazolium fluoride reagent in batch mode led to the development of a fixed-bed continuous flow process, with high conversions.",

author = "Lee, {Jin Kyun} and Fuchter, {Matthew J.} and Williamson, {Rachel M.} and Leeke, {Gary A.} and Bush, {Edward J.} and McConvey, {Ian F.} and Simon Saubern and Ryan, {John H.} and Holmes, {Andrew B.}",

year = "2008",

doi = "10.1039/b808374f",

language = "English",

pages = "4780--4782",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes

AU - Lee, Jin Kyun

AU - Fuchter, Matthew J.

AU - Williamson, Rachel M.

AU - Leeke, Gary A.

AU - Bush, Edward J.

AU - McConvey, Ian F.

AU - Saubern, Simon

AU - Ryan, John H.

AU - Holmes, Andrew B.

PY - 2008

Y1 - 2008

N2 - A high yielding, batch mode synthesis of diaryl ethers and sulfides by an SNAr fluoride-mediated process in scCO2 has been developed; the use of a polymer-supported imidazolium fluoride reagent in batch mode led to the development of a fixed-bed continuous flow process, with high conversions.

AB - A high yielding, batch mode synthesis of diaryl ethers and sulfides by an SNAr fluoride-mediated process in scCO2 has been developed; the use of a polymer-supported imidazolium fluoride reagent in batch mode led to the development of a fixed-bed continuous flow process, with high conversions.

UR - http://www.scopus.com/inward/record.url?scp=54749138355&partnerID=8YFLogxK

U2 - 10.1039/b808374f

DO - 10.1039/b808374f

M3 - Article

C2 - 18830491

AN - SCOPUS:54749138355

SN - 1359-7345

SP - 4780

EP - 4782

JO - Chemical Communications

JF - Chemical Communications

IS - 39

ER -

Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes

Abstract

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