Correlation of superhydrophilicity and photocatalytic activity in the TiQ2-based porous thin films

Seung Yong Chai, Jin Koo Park, Ho Kun Kim, Wan In Lee

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Scopus citations

Abstract

Transparent TiO2, WO3-TiO2, and MoO 3-TiO2 films were prepared by spin-coating each colloidal suspension. The monolayer coverage of WO3 on the surface of TiO 2 greatly increased the photocatalytic activity in the decomposition of gaseous 2-propanol, whereas the addition of MoO3 considerably decreased the photocatalytic reaction of TiO2. For the estimation of superhydrophilicity, the change of contact angles between the water drop and the film surface was measured as a function of UV-irradiation time. The measured contact angle of WO3-TiO2 film was considerably lower than that of TiO2 before the UV-irradiation, and it decreased to the minimum value about 4 times faster than that of pure TiO2 films with the irradiation of UV light. On the other hand, MoO3-TiO2 films showed a low contact angle at initial point, but their contact angle was very slowly decreased under the UV light. The initial low contact angles suggest the high hydrophilic character of WO3-TiO2 and MoO 3-TiO2 films with high Lewis surface acidities. The observed trend suggests that the superhydrophilicity is closely related to the photocatalytic activity.

Original languageEnglish
Title of host publicationEco-Materials Processing and Design VII - Proceedings of the Conference of the 7th International Symposium on Eco-Materials Processing and Design, ISEPD-7
PublisherTrans Tech Publications Ltd
Pages54-57
Number of pages4
ISBN (Print)0878499954, 9780878499953
DOIs
StatePublished - 2006
Event7th International Symposium on Eco-Materials Processing and Design, ISEPD-7 - Chengdu, China
Duration: 8 Jan 200611 Jan 2006

Publication series

NameMaterials Science Forum
Volume510-511
ISSN (Print)0255-5476
ISSN (Electronic)1662-9752

Conference

Conference7th International Symposium on Eco-Materials Processing and Design, ISEPD-7
Country/TerritoryChina
CityChengdu
Period8/01/0611/01/06

Keywords

  • Film
  • Hydrophilicity
  • Photocatalyst
  • Superhydrophilicity

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