Conformational statistics of poly(p-phenylene succinate) (PPSc)

Ji Ho Youk; Dong Il Yoo; Won Ho Jo; Wan Shik Ha

Conformational statistics of poly(p-phenylene succinate) (PPSc)

Ji Ho Youk, Dong Il Yoo, Won Ho Jo, Wan Shik Ha

Research output: Contribution to journal › Article › peer-review

Abstract

The statistical weight parameters of poly(p-phenylene succinate) (PPSc) were determined by the best fit of K_θ which was determined by experiment, and found to be γ=1, σ_κ = 1.4, σ_η, = 1.4 and ω_ηκ = 0.1. The change of conformational entropy (◁S_conf) and enthalpy (◁E_conf) of fusion, and the temperature dependence of unperturbed dimension of PPSc were calculated. Even though ◁S_conf of poly(ethylene terephthalate) (PET) and PPSc were close to each other, the ◁E_conf of PET was positive but that of PPSc was negative. For the temperature dependence of unperturbed dimension, PET showed positive value contrary to negative value for PPSc.

Original language	English
Pages (from-to)	533-541
Number of pages	9
Journal	Polymer (Korea)
Volume	23
Issue number	4
State	Published - 1999
Externally published	Yes

Keywords

Conformational entropy and energy of fusion
Conformational statistics
Poly(p-phenylene succinate) (PPSc)
Temperature dependence of unperturbed dimension
Unperturbed dimension

Cite this

@article{1113b5e063874d1ebccb35c397d3c698,

title = "Conformational statistics of poly(p-phenylene succinate) (PPSc)",

abstract = "The statistical weight parameters of poly(p-phenylene succinate) (PPSc) were determined by the best fit of Kθ which was determined by experiment, and found to be γ=1, σκ = 1.4, ση, = 1.4 and ωηκ = 0.1. The change of conformational entropy (◁Sconf) and enthalpy (◁Econf) of fusion, and the temperature dependence of unperturbed dimension of PPSc were calculated. Even though ◁Sconf of poly(ethylene terephthalate) (PET) and PPSc were close to each other, the ◁Econf of PET was positive but that of PPSc was negative. For the temperature dependence of unperturbed dimension, PET showed positive value contrary to negative value for PPSc.",

keywords = "Conformational entropy and energy of fusion, Conformational statistics, Poly(p-phenylene succinate) (PPSc), Temperature dependence of unperturbed dimension, Unperturbed dimension",

author = "Youk, {Ji Ho} and Yoo, {Dong Il} and Jo, {Won Ho} and Ha, {Wan Shik}",

year = "1999",

language = "English",

volume = "23",

pages = "533--541",

journal = "Polymer (Korea)",

issn = "0379-153X",

publisher = "Polymer Society of Korea",

number = "4",

}

TY - JOUR

T1 - Conformational statistics of poly(p-phenylene succinate) (PPSc)

AU - Youk, Ji Ho

AU - Yoo, Dong Il

AU - Jo, Won Ho

AU - Ha, Wan Shik

PY - 1999

Y1 - 1999

N2 - The statistical weight parameters of poly(p-phenylene succinate) (PPSc) were determined by the best fit of Kθ which was determined by experiment, and found to be γ=1, σκ = 1.4, ση, = 1.4 and ωηκ = 0.1. The change of conformational entropy (◁Sconf) and enthalpy (◁Econf) of fusion, and the temperature dependence of unperturbed dimension of PPSc were calculated. Even though ◁Sconf of poly(ethylene terephthalate) (PET) and PPSc were close to each other, the ◁Econf of PET was positive but that of PPSc was negative. For the temperature dependence of unperturbed dimension, PET showed positive value contrary to negative value for PPSc.

AB - The statistical weight parameters of poly(p-phenylene succinate) (PPSc) were determined by the best fit of Kθ which was determined by experiment, and found to be γ=1, σκ = 1.4, ση, = 1.4 and ωηκ = 0.1. The change of conformational entropy (◁Sconf) and enthalpy (◁Econf) of fusion, and the temperature dependence of unperturbed dimension of PPSc were calculated. Even though ◁Sconf of poly(ethylene terephthalate) (PET) and PPSc were close to each other, the ◁Econf of PET was positive but that of PPSc was negative. For the temperature dependence of unperturbed dimension, PET showed positive value contrary to negative value for PPSc.

KW - Conformational entropy and energy of fusion

KW - Conformational statistics

KW - Poly(p-phenylene succinate) (PPSc)

KW - Temperature dependence of unperturbed dimension

KW - Unperturbed dimension

UR - http://www.scopus.com/inward/record.url?scp=23044491227&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:23044491227

SN - 0379-153X

VL - 23

SP - 533

EP - 541

JO - Polymer (Korea)

JF - Polymer (Korea)

IS - 4

ER -

Conformational statistics of poly(p-phenylene succinate) (PPSc)

Abstract

Keywords

Other files and links

Fingerprint

Cite this